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Purnell equation
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Purnell equation : ウィキペディア英語版
Purnell equation
The Purnell equation is an equation used in analytical chemistry to calculate the resolution ''R''s between two peaks in a chromatogram:〔Miller, J. M., ''Chromatography: Concepts and Contrasts'', second edition, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2005.〕〔Dean, J. R. et al., ''Practical Skills in Chemistry'', first edition, Pearson Education Ltd., Harlow, UK, 2002, p. 205–224.〕〔(C. Legido-Quigley, ''HPLC theory'' )〕
R_s = \frac \left ( \frac \right ) \left ( \frac \right )
where
::''R''s is the resolution between the two peaks
::''N''2 is the plate number of the second peak
::''α'' is the separation factor between the two peaks
::''k'' '2 is the retention factor of the second peak.
The higher the resolution, the better the separation.
==References==



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